个人简介

张庆华,男,教授,博士生导师。197610月生于湖北黄陂,20076月毕业于浙江大学化工系聚合反应工程方向,获工学博士学位,20077月至20099月在浙江大学材料科学与工程博士后流动站从事师资博士后研究工作,201012月晋升副教授,20123月至20133月受浙江大学新星计划资助赴美国华盛顿大学化工系访问研究一年,201712月晋升教授, 兼任浙江大学化工系联合化学反应工程研究所副所长。

Emailqhzhang@zju.edu.cn    TEL: 0571-87953382     办公室:浙江大学玉泉校区 10-5001

研究领域 :化工新材料的设计、制备与性能研究;仿生超浸润界面功能材料;聚合物/纳米复合多孔材料;新能源/锂电池电解质材料;智能响应材料。

 

功能聚合物材料的表面性能主要取决于其界面上特殊的微相形貌和功能性化学基团,具有典型的多尺度效应,同时也是涵盖物理、化学、化工、材料、生物、能源等多学科交叉研究领域。申请人主要针对多尺度界面功能材料的仿生构建与可控制备开展了系统研究,构筑了一系列新型仿生界面功能材料,建立了超浸润型界面功能材料的表面性能与其结构、化学组成之间的关联机制。基于多尺度结构的二元协同效应与精确调控,实现了材料表面物理化学性能的显著提升。作为负责人已承担国家自然科学基金项目5项,省部级科研项目8项,重大横向科技应用开发项目10多项。与中石化及其分公司、中化集团等大型企业保持着长期合作关系,与美国华盛顿大学化工系等国际科研机构开展了良好的合作研究,已发表SCI论文60余篇,获授权发明专利20余项,研究成果发表在AIChE JJ Mater Chem AACS Appl Mater InterLangmuirSoft matterPolymer; Chem Eng J等国际权威期刊上。为Adv Funct Mater; Chem communACS Appl Mater InterMacromoleculesPolym chemJ Mater Chem ALangmuirSoft matterPolymer Ind Eng Chem Res等期刊的特约审稿人。

 

欢迎优秀本科生到本课题组进行科研训练、做SRTP项目及毕业论文!
欢迎有志于新型多尺度/多功能纳米复合材料研究的同学攻读本课题组硕士/博士研究生!
欢迎化工、化学、高分子及生物材料等方向的博士到本课题组开展博士后研究!

 

课题组主页www.cmce.zju.edu.cn


近年代表性论文

2017

       Fu, Y. C.; Jin, B. Y.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., pH-Induced Switchable Superwettability of Efficient Antibacterial Fabrics for Durable Selective Oil/Water Separation. Acs Appl Mater Inter 2017, 9, (35), 30161-30170. 

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       Jiang, J. X.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., Renewable, Biomass-Derived, Honeycomblike Aerogel As a Robust Oil Absorbent with Two-Way Reusability. Acs Sustain Chem Eng 2017, 5, (11), 10307-10316.

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       Jin, B. Y.;  Liu, M. Z.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., Silicone Oil Swelling Slippery Surfaces Based on Mussel-Inspired Magnetic Nanoparticles with Multiple Self-Healing Mechanisms. Langmuir 2017, 33, (39), 10340-10350. 

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       Zhang, Q. H.; Jiang, J. X.; Gao, F.; Zhan, X. L*.; Chen, F. Q., Engineering high-effective antifouling polyether sulfone membrane with P(PEG-PDMS-KH570)@SiO 2 nanocomposite via in-situ sol-gel process. Chem Eng J 2017, DOI: 10.1016/j.cej.2017.03.105.



Zhang, Q. H.; Jin, B.Y.; Wang, B.; Fu, Y.C.; Zhan, X. L*.; Chen, F. Q., Fabrication of high stable superhydrophobic surface with dual scale structure and its anti-frosting properties. Ind Eng Chem Res 2017, 10.1021/acs.iecr.6b04650.
 
Jiang, J. X.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., Novel Amphiphilic Poly(dimethylsiloxane) based Polyurethane Networks tethered with Carboxybetaine and their Combined Antibacterial and Anti-adhesive Property. Appl Surf Sci. 2017, 10.1016/j.apsusc.2017.03.117.
He, Y. B.; Zhang, Q. H.; Zhan, X. L.; Cheng, D. G.; Chen, F. Q., Aluminum impregnated Silica Catalyst for Friedel-Crafts Reaction: Influence of Ordering Mesostructure. Chin J Chem Eng, 2017, doi: 10.1016/j.cjche.2016.11.005.
Fu, Y. C.; Jiang, J. X.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q.,Robust Liquid-repellent Coatings Based on Polymer Nanoparticles with Excellent Self-cleaning and Antibacterial Performances.  J Mater Chem A, 2017, 5, (1), 275-284.
G.F. Zhang, J.X. Jiang, Q.H. Zhang*, X.L. Zhan and F.Q. Chen,Amphiphilic Poly(ether sulfone) Membranes for Oil/Water Separation: Effect of Sequence Structure of the Modifier, Aiche J, 2017,63, (2), 739-750.
2016
Wei, C. Q.; Zhang, G. F., Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., Silicone Oil-Infused Slippery Surfaces Based on SolGel Process-Induced Nanocomposite Coatings: A Facile Approach to Highly Stable Bioinspired Surface for Biofouling Resistance. Acs Appl Mater Inter 2016, 8, (50), 34810-34819.
Y.B. He, Q.H. Zhang*, X.L. Zhan, D.G. Cheng and F.Q. Chen, Synthesis of efficient SBA-15 immobilized ionic liquid catalyst and its performance for Friedel–Crafts reaction, Catal Today, 2016, 276, 112-120.
J.X. Jiang, G.F. Zhang, Q.Y. Wang, Q.H. Zhang*, F. Gao, X.L. Zhan and F.Q. Chen,Novel Fluorinated Polymers containing Short Perfluorobutyl Side Chains and Their Super Wetting Performance on Diverse Substrates, ACS Applied Materials & Interfaces, 2016, 8 (16), 10513–10523.
Wang, B.; Qian, T.; Zhang, Q. H*.; Zhan, X. L.; Chen, F. Q., Heat resistance and surface properties of polyester resin modified with fluorosilicone. Surf Coat Tech 2016, 304, 31-39.
R. He, X.L. Zhan, Q.H. Zhang* and F.Q. Chen, Control of Inclusion Size and Toughness by Reactivity of Multiblock Copolymer in Epoxy Composites, Polymer, 2016, 92, 222-230.
R. He, X.L. Zhan, Q.H. Zhang* and F.Q. Chen, Toughening of epoxy    thermoset with poly[styrene-alt-(maleic acid)]-block-polystyrene-block-poly(n-butyl acrylate) reactive core-shell particles, RSC Advances, 2016, 6, 35621-35627.
T. Qian, J.J. Wang, T.T. Cheng, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, A Novel Block Copolymer with Excellent Amphiphobicity Synthesized via ARGET ATRP, J Polym Sci Part A Polym Chem,2016,54, 2040-2049
 
G.F. Zhang, J.X. Jiang, Q.H. Zhang*, F. Gao, X.L. Zhan and F.Q. Chen,Ultralow Oil-fouling Heterogeneous Poly(Ether Sulfone) Ultrafiltration Membrane via Blending with Novel Amphiphilic Fluorinated Gradient Copolymers, Langmuir, 2016,
G.F. Zhang, F. Gao, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Enhanced oil-fouling resistance of poly(ether sulfone) membrane by incorporating novel amphiphilic zwitterionic copolymers, RSC Advances, 2016, RSC Advances, 2016, 6, 7532-7543
G.F. Zhang, Q.H. Zhang*, Q.Y. Wang, X.L. Zhan and F.Q. Chen, Synthesis and properties of gradient copolymers of butyl methacrylate and fluorinated acrylate via RAFT miniemulsion copolymerizations, J Appl Polym Sci, 133 (2016) 42936-42943
R. He, X.L. Zhan, Q.H. Zhang* and F.Q. Chen, Improving the toughness of epoxy with a reactive tetrablock copolymer containing maleic anhydride, J Appl Polym Sci, 133 (2016) 42826-42833
 
2015
Q.H. Zhang, Q.Y. Wang, J.X. Jiang, X.L. Zhan* and F.Q. Chen, Microphase Structure, Crystallization Behavior, and Wettability Properties of Novel Fluorinated Copolymers Poly(perfluoroalkyl acrylate-co-stearyl acrylate) Containing Short Perfluorohexyl Chains, Langmuir, 31 (2015) 4752-4760.
Q.H. Zhang, H.L. Liu, X.L. Zhan*, F.Q. Chen, J. Yan and H. Tang, Microstructure and antibacterial performance of functionalized polyurethane based on polysiloxane tethered cationic biocides, Rsc Adv, 5 (2015) 77508-77517.
Q.H. Zhang, H.L. Liu, X. Chen, X.L. Zhan* and F.Q. Chen, Preparation, surface properties, and antibacterial activity of a poly(dimethyl siloxane) network containing a quaternary ammonium salt side chain, J Appl Polym Sci, 132 (2015).
X.L. Zhan, G.F. Zhang, X. Chen, R. He, Q.H. Zhang* and F.Q. Chen, Improvement of Antifouling and Antibacterial Properties of Poly(ether sulfone) UF Membrane by Blending with a Multifunctional Comb Copolymer, Ind Eng Chem Res, 54 (2015) 11312-11318.
Y.Q. Tang, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Superhydrophobic and anti-icing properties at overcooled temperature of a fluorinated hybrid surface prepared via a sol-gel process, Soft Matter, 11 (2015) 4540-4550.
Y.B. He, C. Wan, Q.H. Zhang*, X.L. Zhan, D.G. Cheng and F.Q. Chen, Durability enhanced ionic liquid catalyst for Friedel-Crafts reaction between benzene and 1-dodecene: insight into catalyst deactivation, Rsc Adv, 5 (2015) 62241-62247.
F. Gao, G.F. Zhang, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Improved Antifouling Properties of Poly(Ether Sulfone) Membrane by Incorporating the Amphiphilic Comb Copolymer with Mixed Poly(Ethylene Glycol) and Poly(Dimethylsiloxane) Brushes, Ind Eng Chem Res, 54 (2015) 8789-8800.
T.T. Cheng, R. He, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Magnetic particle-based super-hydrophobic coatings with excellent anti-icing and thermoresponsive deicing performance, J Mater Chem A, 3 (2015) 21637-21646.
X. Chen, G.F. Zhang, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Preparation and Performance of Amphiphilic Polyurethane Copolymers with Capsaicin-Mimic and PEG Moieties for Protein Resistance and Antibacteria, Ind Eng Chem Res, 54 (2015) 3813-3820.
 
2014
X.L. Zou, Y.J. Lan, Q.H. Zhang and X.L. Zhan*, Synthesis and Mechanical Properties of Polyacrylic Acid Resin Retanning Agent, J Soc Leath Tech Ch, 98 (2014) 127-130.
X.L. Zou, Y.J. Lan, Q.H. Zhang, Z.Y. Li and X.L. Zhan*, Effects of Polyacrylic Acid on the Structure of Collagen Fibre, J Soc Leath Tech Ch, 98 (2014) 172-176.
Q.H. Zhang, Q.Y. Wang, X.L. Zhan* and F.Q. Chen, Synthesis and Performance of Novel Fluorinated Acrylate Polymers: Preparation and Reactivity of Short Perfluoroalkyl Group Containing Monomers, Ind Eng Chem Res, 53 (2014) 8026-8034.
X.L. Zhan, G.F. Zhang, Q.H. Zhang* and F.Q. Chen, Preparation, Surface Wetting Properties, and Protein Adsorption Resistance of Well-Defined Amphiphilic Fluorinated Diblock Copolymers, J Appl Polym Sci, 131 (2014).
X.L. Zhan, Y.D. Yan, Q.H. Zhang* and F.Q. Chen, A novel superhydrophobic hybrid nanocomposite material prepared by surface-initiated AGET ATRP and its anti-icing properties, J Mater Chem A, 2 (2014) 9390-9399.
X.L. Zhan, R. He, Q.H. Zhang* and F.Q. Chen, Microstructure and mechanical properties of amphiphilic tetrablock copolymer elastomers via RAFT miniemulsion polymerization: influence of poly[styrene-alt-(maleic anhydride)] segments, Rsc Adv, 4 (2014) 51201-51207.
Y.D. Yan, N.Z. Luo, X.G. Xiang, Y.M. Xu, Q.H. Zhang* and X.L. Zhan, Fabricating Mechanism and Preparation of Anti-Icing & Icephobic Coating, Prog Chem, 26 (2014) 214-222.
 
2013
Y.T. Yu, Q.H. Zhang*, X.L. Zhan* and F.Q. Chen, Interfacially Confined RAFT Miniemulsion Copolymerization of Styrene and Butadiene, J Appl Polym Sci, 127 (2013) 2557-2565.
Z.X. Wang, Q.H. Zhang*, X.L. Zhan, F.Q. Chen, G.H. Rao and J.H. Xiong, Preparation, kinetics and microstructures of well-defined PS-b-PS/Bd diblock copolymers via RAFT miniemulsion polymerization, J Polym Res, 20 (2013).
T. Qian, J.J. Wang, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Synthesis and Characterization of Gradient Copolymer Composed of [N-Methyl-perfluorohexane-1-sulfonamide] Ethyl Acrylate and MMA, Chem J Chinese U, 34 (2013) 703-707.
 
2012
Q.H. Zhang, Y. Shi, X.L. Zhan* and F.Q. Chen, In situ miniemulsion polymerization for waterborne polyurethanes: Kinetics and modeling of interfacial hydrolysis of isocyanate, Colloid Surface A, 393 (2012) 17-26.
X.L. Zhan, B. Chen, Q.H. Zhang*, L.M. Yi, B. Jiang and F.Q. Chen, Synthesis and characterization of amphiphilic PMTFPS-b-PEO diblock copolymers, J Appl Polym Sci, 123 (2012) 3620-3626.
Y.T. Yu, Q.H. Zhang*, X.L. Zhan and F.Q. Chen, Comparison of styrene reversible addition-fragmentation chain-transfer polymerization in a miniemulsion system stabilized by ammonlysis poly(styrene-alt-maleic anhydride) and sodium dodecyl sulfate, J Appl Polym Sci, 124 (2012) 4249-4258.
Y.T. Yu, Q.H. Zhang*, Z.X. Wang, X.L. Zhan, R. He, W.T. Zhang and F.Q. Chen, Synthesis of Surface-Functionalized Poly(styrene-co-butadiene) Nanoparticles via Controlled/Living Radical Mini-emulsion Copolymerization Stabilized by Ammonolyzed Poly(styrene-alt-maleic anhydride) (SMA) RAFT Agent, J Macromol Sci A, 49 (2012) 60-66.